Journal
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
Volume 158, Issue 2, Pages 515-520Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/S1381-1169(99)00445-8
Keywords
palladium; heterogeneous hydrogenation; cross-linked polymers
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The catalytic activity of the cross-linked polymer obtained by reaction of Pd(AAEMA)(2) [HAAEMA=2 (acetoacetoxy)ethyl methacrylate] and suitable acrylates as comonomers and cross-linkers was investigated in the hydrogenation reactions of substrates such as olefins, aromatic and unsaturated aldehydes, unsaturated ketones and nitrocompounds. The polymer-supported palladium was found to be active and recyclable without loss of metal. (C) 2000 Elsevier Science B.V. All rights reserved.
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