Journal
CHEMICAL PHYSICS LETTERS
Volume 328, Issue 1-2, Pages 124-128Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/S0009-2614(00)00921-0
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The stretched exponential (SE) and the power law (PL), fitting equally well the disulfide recombination of a de-novo peptide, differ markedly in estimation of thiyl radical population. This leads to quite different lifetime distribution functions encompassing about 20% (ES) or 70% (PL) of the radicals. For inhomogeneous recombination kinetics, the interpretation of the PL in terms of superposition of first-order decays is compared with that in terms of superposition of second-order decays. (C) 2000 Elsevier Science B.V. All rights reserved.
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