Journal
TETRAHEDRON
Volume 56, Issue 40, Pages 7859-7868Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4020(00)00708-0
Keywords
epothilones; aldol reaction; enantioselectivity
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Enantioselective syntheses of differentially protected C-1-C-6 fragments, (3S)-3-hydroxy-4,4-dimethyl-5-oxoheptanoic acid 4, (5S)-7-[1,1-bis(mechylethyl)-2-methyl-1 -silapropoxy]-5-hydroxy-4,4-dimethylheptan-3-one 5 and (4S)-2-(2,2-dimethyl-1,3-dioxan-4-yl)-2-methylpentan-3-one 23, common to both epothilones A and B, are reported. (C) 2000 Elsevier Science Ltd. All rights reserved.
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