4.4 Article

Synthesis and self-assembly of a novel tetrapyrrole containing dipyrrin units linked at the 3,3′-positions

Journal

TETRAHEDRON LETTERS
Volume 41, Issue 40, Pages 7717-7721

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(00)01305-8

Keywords

tetrapyrrole; self-assembly; dipyrrin; 3,3 '-dipyrromethane; ligand

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A novel ligand comprising two dipyrrin units linked by a CH2 spacer at the 3-position has been synthesized and used to prepare a double-stranded helical assembly. Its structure was confirmed by X-ray analysis. A new approach to 3,3'-linked dipyrromethanes with CH2 as the spacer is also reported. (C) 2000 Elsevier Science Ltd. All rights reserved.

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