4.3 Article

Intercalation of spirooxazine induced by zinc cation chelation in montmorillonite and its photochromic behavior

Journal

CHEMISTRY LETTERS
Volume -, Issue 10, Pages 1142-1143

Publisher

CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2000.1142

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Spirooxazine (SPO) was introduced into hydrophobically modified montmorillonite dispersed in acetone under UV illumination in the presence of zinc ions. The fluorescence spectra of the samples exhibited photochromic behavior arising from the photoinduced interconversion between the original species of SPO and the Zn-chelated complex of the SPO-derived merocyanine.

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