Formation and size control of sliver nanoparticles by laser ablation in aqueous solution

Silver nanoparticles were produced by laser ablation of a metal silver plate in an aqueous solution of sodium dodecyl sulfate, C12H25OSO3Na. The absorption spectrum of the silver nanoparticles is found to be essentially the same as that of silver nanoparticles chemically prepared in a solution. The size distribution of the nanoparticles measured by an electron microscope shifts to a smaller size with increase in the concentration of sodium dodecyl sulfate and with a decrease in the irradiation laser power. These findings are explained by a scheme that the nanoparticles are formed via rapid formation of an embryonic silver particle and a consecutive slow particle growth in competition with termination of the growth due to SDS coating on the particle.