Journal
SCIENCE
Volume 290, Issue 5489, Pages 117-118Publisher
AMER ASSOC ADVANCEMENT SCIENCE
DOI: 10.1126/science.290.5489.117
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The first metal-xenon compound with direct gold-xenon bonds is achieved by reduction of AuF3 with elemental xenon. The square planar AuXe42+ cation is established by a single-crystal structure determination, with a gold-xenon bond Length of approximately 274 picometers. The bonding between gold and xenon is of the a donor type, resulting in a charge of approximately 0.4 per xenon atom.
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