4.4 Article

Palladium-catalyzed arylation of butadiynes

Journal

TETRAHEDRON LETTERS
Volume 41, Issue 43, Pages 8259-8262

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(00)01474-X

Keywords

arylation; butadiynes; butatrienes; domino processes; palladium catalysis

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Diarylbutadiynes 1 undergo a palladium-catalyzed coupling reaction with aryl halides 2 to give tetraarylbutatrienes 3, which may further react to benzofulvenes 6 depending on the reaction temperature and the type of aryl groups. (C) 2000 Elsevier Science Ltd. All rights reserved.

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