Journal
TETRAHEDRON
Volume 56, Issue 44, Pages 8735-8746Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4020(00)00803-6
Keywords
guanidines; amidines; molecular recognition; axial chirality
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Axially chiral amidines and guanidines. some possessing C-2-symmetry, have been targeted as potential chiral catalysts for reactions of alpha,beta -unsaturated carboxylic acids or esters. The key step in each synthesis required the coupling of two sterically demanding aromatic compounds to form atropisomeric biaryl species. (C) 2000 Elsevier Science Ltd. All rights reserved.
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