Journal
FLUID PHASE EQUILIBRIA
Volume 175, Issue 1-2, Pages 229-236Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/S0378-3812(00)00449-0
Keywords
vapor-liquid equilibria; data; vapor pressure; azeotrope; Bancroft point; equation of state
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Vapor-liquid equilibria data from the literature for the system benzene + isopropanol are reviewed in detail. The data span a pressure range from 0.1 to 4.1 MPa, and indicate azeotropic behavior with the composition of the azeotrope shifting from being benzene-rich at low pressure to isopropanol-rich at high pressure. We attribute this behavior to the nature of the Bancroft point in this system and discuss the prevalence of Bancroft points in general. In a study comprising 1350 pure components, 64,103 Bancroft points were identified. (C) 2000 Published by Elsevier Science B.V.
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