Journal
ORGANOMETALLICS
Volume 19, Issue 23, Pages 4921-4924Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om000584d
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The cothermolysis of pivaloyl- and adamantoyltris(trimethylsilyl)silane with bis(trimethylsilyl)acetylene, bis(dimethylphenylsilyl)acetylene, and bis(methyldiphenylsilyl)acetylene afforded the respective adducts, silacyclopropenes, probably via isomerization of [2 + 2] cycloadducts arising from the reactions of silenes formed thermally from acylpolysilanes with bis(silyl)acetylenes. Thermolysis of the silacyclopropene formed from pivaloyltris(trimethylsilyl)silane and bis(trimethylsilyl)acetylene with 2,3-dimethyl-1,3-butadiene gave a 3,4-dimethyL-1-silacyclopent-3-ene derivative.
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