Journal
PHYSICAL REVIEW A
Volume 62, Issue 6, Pages -Publisher
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevA.62.062506
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The role of avoided crossings for resonant x-ray Raman scattering is explored. The strong dependence of the electronic transition amplitudes on internuclear distance at avoided crossings causes new, and even anomalous, spectral features, and can bring about a breakdown of the generally accepted participator or spectator classification of the transitions. We report, and apply the theory on, an experimental observation of the electron decay of the N 1s-->pi* core-excited level in N-2 the B(2)Sigma (+)(u) final state with peculiar, non-Franck-Condon, vibrational intensity distributions.
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