Journal
CURRENT OPINION IN CHEMICAL BIOLOGY
Volume 4, Issue 6, Pages 710-714Publisher
CURRENT BIOLOGY LTD
DOI: 10.1016/S1367-5931(00)00149-6
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The microenvironment of immobilized transition metal catalysts can be manipulated using catalyst-substrate conjugates in combination with the technology of molecular imprinting. Recent results have shown that catalysts with a significantly enhanced activity combined with an improved substrate-, regio- and enantioselectivity can be prepared in this way. These artificial systems resemble metalloenzymes because the catalytic transformation is effectively controlled by a well-defined second coordination sphere.
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