Journal
COORDINATION CHEMISTRY REVIEWS
Volume 210, Issue -, Pages 11-45Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/S0010-8545(00)00315-5
Keywords
silicon derivatives; silyllithium compounds; group I metals; dendrimer; polysilane
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An account is given of the preparation and structural investigations of silyllithium compounds, including X-ray and NMR data. This review covers the chemistry of lithiosilanes with alkyl, aryl, functional substituents and lithiooligosilanes with Si-Si bonds. Application of lithiosilanes for the synthesis of polysilane dendritic molecules is also described. (C) 2000 Elsevier Science B.V. All rights reserved.
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