Journal
ACS APPLIED MATERIALS & INTERFACES
Volume 7, Issue 41, Pages 23110-23116Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsami.5b06819
Keywords
perovskite solar cells; lead acetate; chlorine incorporation; grain size; crystallinity; solvent annealing
Funding
- Research Grants Council of the Hong Kong Special Administrative Region, China [T23-713/11]
- National Natural Science Foundation of China [21303150, 51473138]
Ask authors/readers for more resources
We show the effects of chlorine incorporation in the crystallization process of perovskite film based on a lead acetate precursor. We demonstrate a fabrication process for fast grain growth with highly preferred 11101 orientation upon only 5 min of annealing at 100 degrees C. By studying the correlation between precursor composition and morphology, the growth dynamic of perovskite film in the current system is discussed. In particular, we found that both lead acetate precursor and Cl incorporation are beneficial to perovskite growth. While lead acetate allows fast crystallization process, Cl improves perovsldte crystallinity. Planar perovskite solar cells with optimized parameters deliver a best power conversion efficiency of 15.0% and average efficiency of 14.0% with remarkable reproducibility and good stability.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available