Journal
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING
Volume 294, Issue -, Pages 715-718Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/S0921-5093(00)01057-1
Keywords
icosahedral; quasicrystal; thermal conductivity; thermopower; electrical conductivity
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We report on measurements of the temperature dependence of the electrical resistivity rho, the thermopower S, and the thermal conductivity lambda of single grained RE-Mg-Zn (RE=Y, Tb, Ho, Er) icosahedral quasicrystals between 5 acid 300 K. The resistivity of all four samples is very weakly temperature dependent with a negative slope d rho /dT. The S/T versus temperature curves exhibit a maximum at temperatures between 12 and 15 K. This feature is observed for all here investigated quasicrystalline materials. The appearance of a maximum in the thermal conductivity of (Y, Ho, Er)-Mg-Zn, and a plateau in that of Tb-Mg-Zn is ascribed to a power-law temperature dependence of the mean free path of delocalized quasilattice excitations at intermediate temperatures. A progressive suppression of the maximum in the thermal conductivity data as the de Gennes factor increases indicates for a coupling of the spin system to the lattice. (C) 2000 Elsevier Science B.V. All rights reserved.
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