Journal
BIOCONJUGATE CHEMISTRY
Volume 20, Issue 11, Pages 2001-2016Publisher
AMER CHEMICAL SOC
DOI: 10.1021/bc900087a
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In this review, the synthesis and application of biomedical and pharmaceutical polymers synthesized via the copper(I)-catalyzed alkyne-azide cycloaddition, the thiol-ene reaction, or a combination of both click reactions are discussed. Since the introduction of both click methods, numerous articles have disclosed new approaches for the synthesis of polymers with different architectures, e.g., block and graft copolymers, dendrimers, and hydrogels, for pharmaceutical and biomedical applications. By describing selected examples, an overview is given of the possibilities and limitations that these two click methods may offer.
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