4.4 Article

Synthetic studies on ciguatoxin - Synthesis of H-I-J ring system

Journal

TETRAHEDRON
Volume 56, Issue 52, Pages 10209-10219

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4020(00)00865-6

Keywords

ciguatoxin; acetylene biscobalthexacarbonyl complex; cyclization

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Synthesis of a tricyclic ring system corresponding to H-I-J rings of ciguatoxin was stereoselectively achieved in 13 steps from a sugar derivative as a model study directed toward the total synthesis of ciguatoxin. (C) 2000 Elsevier Science Ltd. All rights reserved.

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