4.8 Article

Control of chirality of an azobenzene liquid crystalline polymer with circularly polarized light

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 122, Issue 51, Pages 12646-12650

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja001244m

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Irradiation with circularly polarized light of a film of an achiral azobenzene liquid crystalline polymer induces chirality. Circularly polarized light with opposite handedness produces enantiomeric structures. A chirooptical switch based on this phenomenon is reported.

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