Journal
ORGANIC LETTERS
Volume 2, Issue 26, Pages 4233-4236Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol006791r
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[GRAPHICS] We report the first example of enantioselective aldehyde additions of 2-methyl-3-butyn-2-ol, a commodity bulk chemical that is readily available. Following a facile fragmentation reaction, the addition reactions provide access to optically active terminal acetylenes as useful building blocks for asymmetric synthesis.
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