Journal
ORGANIC LETTERS
Volume 3, Issue 1, Pages 61-64Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol006769y
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[GRAPHICS] Alkylidenesilacyclopentanes (formed by intramolecular hydrosilylation of homopropargyl alcohols) are efficiently coupled with aryl or alkenyl halides in the presence of tetrabutylammonium fluoride and a palladium(0) catalyst. Yields of cross-coupling were generally high, and the reaction is compatible with a wide range of functional groups. The overall transformation achieves the conversion of homopropargyl alcohols to trisubstituted homoallylic alcohols in a highly stereoselective fashion.
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