4.4 Article

Nickel catalysed electrosynthesis of ketones from organic halides and iron pentacarbonyl.: Part 2:: Unsymmetrical ketones

Journal

TETRAHEDRON
Volume 57, Issue 3, Pages 525-529

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4020(00)01017-6

Keywords

metal carbonyl; ketone electrosynthesis; nickel catalysis; organic halides electroreduction

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Unsymmetrical aryl-benzyl or aryl-alkyl ketones are obtained by electrolysing in an undivided cell a DMF solution containing two organic halides, iron pentacarbonyl and a catalytic amount of a nickel-2,2'-bipyridine complex. (C) 2001 Elsevier Science Ltd. An rights reserved.

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