Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 617, Issue 1, Pages 47-55Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/S0022-328X(00)00599-4
Keywords
C-H activation; rhodium carbenoid; chiral catalysts
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Intermolecular C-H insertion with rhodium carbenoid intermediates is a very promising method for C-H activation. By using carbenoids derived from vinyl and phenyl diazoacetates, highly selective C-H insertions can be achieved. High asymmetric induction is obtained when dirhodium tetraprolinates (24-27) are used as catalysts. Remarkably, with certain substrates, excellent diastereocontrol is also possible. (C) 2001 Elsevier Science B.V. All rights reserved.
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