Journal
SYNTHETIC METALS
Volume 116, Issue 1-3, Pages 343-347Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/S0379-6779(00)00434-3
Keywords
photovoltaics; polyelectrolytes; ionically self-assembled monolayers; poly(para-phenylene-vinylene); fullerenes
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We use the technique of ionically self-assembled monolayers (ISAMs) to produce photovoltaic devices of well-controlled thickness and composition. The ISAM nanostructure fabrication method simply involves the alternate dipping of a charged substrate into aqueous cationic and anionic solutions at room temperature. We have employed several approaches to combine the tetrahydrothiophenium precursor of poly(para-phenylene-vinylene) (PPV) with fullerenes and other organic materials. We apply modulation spectroscopy for the electrooptical characterization of the ISAM-devices. The modulation frequency dependence of the photocurrent can be assigned to the influence of trapped charges taking Dart in the photovoltaic process. (C) 2001 Published by Elsevier Science B.V.
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