4.8 Article

Catalytic ethenylation reaction of phenol using SnCl4

Journal

ORGANIC LETTERS
Volume 3, Issue 2, Pages 241-242

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol006888d

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[GRAPHICS] Ethenylation reaction of phenol with silylethyne at the o-position is catalyzed by the SnCl4-BuLi reagent. While turn over numbers (TONs) in the reactions of m- or p-substituted phenols are 3 to 4, those for o-substituted phenols are 8 to 9.

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