Journal
TETRAHEDRON LETTERS
Volume 42, Issue 6, Pages 1025-1028Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(00)02145-6
Keywords
asymmetric synthesis; phosphonic acids and derivatives; Michael addition
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A simple and general asymmetric synthesis of beta -amidophosphonates is described. The method involves the highly selective addition (up to 95% d.e.) of diethyl phosphite to various chiral alpha,beta -unsaturated carboxylic amides derived from chiral aminoalcohols. (C) 2001 Elsevier Science Ltd. All rights reserved.
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