Journal
ORGANIC LETTERS
Volume 3, Issue 3, Pages 421-424Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol0069296
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[GRAPHICS] Low-valent rhodium complexes are efficient catalysts for the activation of alpha -C-H bond of isonitriles. Addition of isonitriles to carbonyl compounds proceeds under mild and neutral conditions to give the corresponding alpha,beta -unsaturated formamides. Catalytic synthesis of pyrroles can be performed by cyclocondensation of isonitriles with 1,3-dicarbonyl compounds.
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