4.8 Article

Organolanthanide-catalyzed cyclization/boration of 1,5-and 1,6-dienes

Journal

ORGANIC LETTERS
Volume 3, Issue 3, Pages 361-363

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol006841s

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Funding

  1. NIGMS NIH HHS [GM48580] Funding Source: Medline

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[GRAPHICS] 1,5- and 1,6-Dienes undergo a cyclization/boration reaction in the presence of a catalytic amount of Cp*Sm-2 . THF. The resulting organoboranes can be oxidized to the corresponding primary cyclic alcohols using standard conditions.

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