4.8 Article

Enantioselective rhodium(I)-catalyzed hydrogenation of trifluoromethyl ketones

Journal

ORGANIC LETTERS
Volume 3, Issue 3, Pages 457-459

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol006962s

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[GRAPHICS] The asymmetric hydrogenation of trifluoromethyl ketones to yield chiral alpha -trifluoromethyl alcohols with enantiomeric excesses up to 98% was achieved in the presence of chiral rhodium-(amidephosphine-phosphinite) complexes.

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