4.8 Article

Time-temperature superposition in viscous liquids

Journal

PHYSICAL REVIEW LETTERS
Volume 86, Issue 7, Pages 1271-1274

Publisher

AMERICAN PHYSICAL SOC
DOI: 10.1103/PhysRevLett.86.1271

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Dielectric relaxation measurements on supercooled triphenyl phophite show that time-temperature superposition (TTS) is obeyed fur the primary relaxation process at low temperatures. Measurements on other molecular liquids close to the calorimetric glass transition indicate that TTS is linked to an omega (-1/2) high-frequency decay of the loss, while the loss peak width is nonuniversal.

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