Journal
PHYSICAL REVIEW B
Volume 63, Issue 10, Pages -Publisher
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevB.63.100406
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The magnetic, transport, and structural investigations of the CaMn1-xMoxO3 manganites show that orbital and charge ordering are induced by Mn-site doping in pure calcium based manganites. Starting from a cluster glass behavior at x approximate to0.04, orbital ordering is evidenced for x approximate to0.10, whereas charge ordering (characterized by an incommensurate structure with q approximate to0.02-0.25) is obtained for x approximate to0.12 with a high-T(Co)approximate to 300 K. This charge ordering effect induced by Mo doping is interpreted in terms of a high valency effect.
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