4.4 Article

Ligand electronic effects on rates of copper mediated atom transfer radical cyclisation and polymerisation

Journal

TETRAHEDRON LETTERS
Volume 42, Issue 10, Pages 2003-2005

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(01)00061-2

Keywords

radicals and radical reactions; cyclisations; copper and compounds; polymers

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The effect of different N-pentyl-2-pyridylmethanimine derivatives 2a-f upon the rate of copper(I) mediated atom transfer radical cyclisation (ATRC) of 5 and living atom transfer radical polymerisation (ATRP) of methylmethacrylate were investigated. (C) 2001 Elsevier Science Ltd. All rights reserved.

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