4.4 Article

Ruthenium complex catalyzed hydrosilylation of esters: a facile transformation of esters to alkyl silyl acetals and aldehydes

Journal

TETRAHEDRON LETTERS
Volume 42, Issue 11, Pages 2149-2151

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(01)00094-6

Keywords

ruthenium and compounds; catalysts; silicon and compounds; esters; acetals; aldehydes

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Hydrosilylation of esters takes place in the presence of ruthenium catalysts to afford the corresponding alkyl silyl acetals in moderate to good yields, which can be converted into aldehydes by hydrolysis. (C) 2001 Elsevier Science Ltd. All rights reserved.

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