Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 622, Issue 1-2, Pages 259-264Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/S0022-328X(00)00929-3
Keywords
Schiff bases; imines; macrocyclic boronates; self-assembly
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In order to investigate the formation of macrocyclic boronates, we carried out the reaction of 3-aminophenyl boronic acid with salicylaldehyde, 2-hydroxyacetophenone and 2-hydroxybenzophenone. In all cases, macrocyclic structures were formed and the X-ray crystallographic study of the trimeric complex derived from 2-hydroxyacetophenone showed that the macrocyclic system is asymmetric. (C) 2001 Published by Elsevier Science B.V. All rights reserved.
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