4.6 Article

Simulation of SNIFTIRS experiments

Journal

JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume 500, Issue 1-2, Pages 471-478

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/S0022-0728(00)00486-1

Keywords

SNIFTIRS; pyridine; Au(111) electrode vertical bar solution interface

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We present a simulation of subtractively normalized interfacial Fourier transform infrared spectra (SNIFTIRS) for the case of pyridine adsorbed at the Au(111) electrode. From experimental data and SNIFTIRS simulation the tilt angles can be evaluated as a function of the electrode potential for pyridine molecules adsorbed on terrace and defect sites, providing a detailed view of the site and potential dependent molecular orientation. (C) 2001 Elsevier Science B.V. All rights reserved.

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