Journal
TETRAHEDRON
Volume 57, Issue 12, Pages 2379-2383Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4020(01)00114-4
Keywords
allylic alchols; isomerization; catalysis; iron
Categories
Ask authors/readers for more resources
The direct conversion of allylic alcohols to saturated carbonyls, using Fe(CO)(5) as a catalyst, offers good synthetic potential. Mono-, di- and even trisubstituted alkenes bearing various alkyl, aryl and electronwithdrawing groups on the allylic system give good to excellent yields of rearranged products. Limitations occur mainly with polyunsaturated derivatives. This reaction was applied to a short and efficient synthesis of cyclamen aldehyde and foliaver. (C) 2001 Elsevier Science Ltd. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available