Journal
ORGANIC LETTERS
Volume 3, Issue 6, Pages 869-872Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol015505o
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[GRAPHICS] A series of chiral oxovanadium(IV) complexes derived from tridentate N3,5-substituted and N-3,4-benzo- and N-5,6-benzo-salicylidene-alpha -amino acids can serve as efficient catalysts for the enantioselective oxidative couplings of various 3-, 6-, and 7-substituted 2-naphthols under O-2 The best scenario involves the use of a vanadyl complex arising from 2-hydroxy-1-naphthaldehyde and valine (or phenylalanine) in CCl4, leading to BINOLs in good yields (75-100%) and with enantioselectivities of up to 68%.
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