Photoinduced phase transition to a new macroscopic spin-crossover-complex phase

We clarified for the first time that the photoinduced phase is quite different in structure from the thermally induced phase by the resonant Raman spectroscopy in the spin-crossover complex, [Fe(2-pic)(3)]-Cl2EtOH. In the photoinduced phase we observed a number of additional lines assigned to infraactive vibrational modes which are strongly prohibited by selection rules in the thermally induced phase. These results indicate that a dramatic symmetry lowering should take place in the photoinduced phase. The cooperative Jahn-Teller transformation is a plausible candidate for the symmetry lowering in the photoinduced phase.