Journal
TETRAHEDRON
Volume 57, Issue 13, Pages 2515-2520Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4020(01)00077-1
Keywords
enantioselection; fluorescence; helicenes; molecular recognition
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The helical diol 2,15-dihydroxy-hexahelicene (HELIXOL) is an excellent fluorescence sensor for chiral amines and amino alcohols. The fluorescence of HELIXOL can be efficiently as well as enantioselectively quenched by the enantiomers of several chiral amines and amino alcohols. Its high fluorescence intensity and its ability to enantiodiscriminate effectively makes it potentially useful for high-throughput screening of ee. (C) 2001 Elsevier Science Ltd. All rights reserved.
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