Journal
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
Volume 169, Issue 1-2, Pages 47-56Publisher
ELSEVIER
DOI: 10.1016/S1381-1169(00)00563-X
Keywords
Ru-alkylidene; MCM-41 materials; heterogeneous catalysis; ring opening metathesis polymerisation; ring closing metathesis
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Heterogeneous hybrid catalysts with respect to the metathesis of olefins have been prepared by ligand exchange reaction between Ru-alkylidene complexes (Grubbs' type) and a phosphinated mesoporous matrix (P-MCM-41). The host/guest interaction is studied by FT-Raman, thermogravimetric analysis and N-2 adsorption. Catalytic tests in olefin metathesis reveal ROMP activity towards norbornene, even in aquatic environment, and a very high activity for the RCM of diallylamine and diethyldiallylmalonate. (C) 2001 Elsevier Science B.V. All rights reserved.
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