Journal
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2
Volume -, Issue 4, Pages 557-562Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b007912j
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H-1 and C-13 NMR investigations have been carried out in order to elucidate the products of oxidation of 6-hydroxydopamine [5-(2-aminoethyl)benzene-1,2,4-triol, protonated form H3LH+]. Stopped-flow, NMR kinetic experiments, and quantum mechanical calculations were employed as additional aids to the interpretation of the results. Evidence is provided that, at low pH, three quinones are produced that are in metastable equilibrium, namely the p- (pQ), o- (oQ), and triketo-quinones (tQ). Results obtained with sodium periodate and iron(III) are compared and-discussed. At higher pHs (>2.5) the quinones reach rapid equilibrium because they start to deprotonate, all giving rise to the same species (Q(-)), which is the only species detectable above a pH of about 6 and which is stable over a large pH range.
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