Journal
COORDINATION CHEMISTRY REVIEWS
Volume 214, Issue -, Pages 43-90Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/S0010-8545(00)00384-2
Keywords
low-valent Tc; metal-nitrogen multiple bonds; oxo-complexes; technetium complexes; X-ray structures
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This paper investigates the structural aspects of technetium-containing complexes. The focus is on the description of the various coordination environments around the technetium center. The complexes are divided according to the coordination sphere and the most significant structural parameters are reviewed and discussed. The review covers the crystallographic determinations published in the years between 1993 and 1999. (C) 2001 Elsevier Science B.V. All rights reserved.
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