Journal
WATER RESEARCH
Volume 35, Issue 6, Pages 1599-1602Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0043-1354(00)00397-3
Keywords
DBP; disinfection by-product; drinking water analysis; GC/MS; haloacetic acid
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Haloacetic acids (HAAs) are a group of disinfection by-products formed in chlorinated water. Due to their potential health effects and widespread occurrences, HAAs are regulated in drinking water in the United States under a promulgated regulation To better control the formation of HAAs in drinking water, a reliable and accurate analytical method is needed for HAA monitoring. In the present study, a liquid-liquid microextraction, acidic methanol derivatization, and gas chromatography/mass spectrometry (GC/MS) detection method was developed for determining HAAs and dalapon in drinking water. The newly developed method is capable of analyzing all nine HAAs and dalapon at mug/l levels. The method performance, including the method detection limit (MDL) and spiking recovery, was evaluated. In comparison to EPA Method 552.2, which uses gas chromatography/electron capture detection (GC/ECD), this GC/MS method gave cleaner baselines and had few interfering peaks. For each of all nine HAAs and dalapon, the MDL was less than 1 mug/l and the spiking recovery ranged from 73 to 165%. Using the GC/MS method, the run time could also be significantly reduced without compromising the analytical results. Further study is needed to fine-tune this GC/MS based analytical method, especially in the detection of brominated trihaloacetic acids and monochloroacetic acid. (C) 2001 Elsevier Science Ltd. All rights reserved.
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