4.8 Article

A xanthate transfer radical process for the introduction of the trifluoromethyl group

Journal

ORGANIC LETTERS
Volume 3, Issue 7, Pages 1069-1071

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol0156446

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[GRAPHICS] S-Trifluoromethyl xanthates efficiently add to unactivated alkenes by a radical mechanism to give adducts with a trifluoromethyl group at the least hindered terminus of the olefin.

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