Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 66, Issue 7, Pages 2434-2441Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo001710q
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A novel sulfenylation method induced by aromatization of quinone mono-O,S-acetals is described. These sulfenylation reagents readily react with silyl enolethers or electron rich aromatic compounds to give sulfenylation products under mild conditions. In particular, O,S-acetal 2j, which possesses a pentafluorophenylthio function, is the most effective reagent from the standpoint of the adaptability for various substrates.
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