Journal
TETRAHEDRON LETTERS
Volume 42, Issue 15, Pages 2763-2766Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(01)00300-8
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The scope of borane-amine adducts as reducing agents is broadened through palladium-catalyzed methanolysis capable of reducing a wide variety of functional groups. Hence, borane mediated reduction of a benzamide followed by a tandem methanolysis/hydrogenolysis of the resulting borane-benzylamine adduct allows chemoselective removal of an N-benzoyl in the presence of an O-benzoyl. (C) 2001 Elsevier Science Ltd. All rights reserved.
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