4.4 Article

Enantioselective hydrogenation with inexpensive, easily available monodentate phosphite ligands

Journal

TETRAHEDRON LETTERS
Volume 42, Issue 15, Pages 2897-2899

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(01)00319-7

Keywords

asymmetric hydrogenation; monodentate phosphites; rhodium catalysts; racemic binaphthol; menthol

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Diastereomerically pure menthyl binaphthylphosphite ligands, easily accessible from the inexpensive, racemic binaphthol, L-menthol and PCl3, are shown to be effective in the rhodium-catalysed enantioselective hydrogenation of prochiral olefins. (C) 2001 Published by Elsevier Science Ltd.

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