Journal
TETRAHEDRON LETTERS
Volume 42, Issue 16, Pages 2931-2932Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(01)00336-7
Keywords
carbamoylsilane; siloxyaminocarbene; carbamoylsilylation
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A carbamoylsilane behaves as a siloxyaminocarbene towards electrophilic reagents, undergoing C-H insertion with chloroform, methyl propiolate and 1-chloro-2,4-dinitrobenzene. Its reaction with DMAD results in carbamoylsilylation. (C) 2001 Published by Elsevier Science Ltd.
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