Journal
TETRAHEDRON-ASYMMETRY
Volume 12, Issue 6, Pages 959-963Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0957-4166(01)00150-1
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1.3-Bis-(trimethylsilyloxy)-1-methoxy-buta-1,3-diene (Chan's diene) can be conveniently used in asymmetric aldol reaction with aromatic, heteroaromatic, alpha,beta -unsaturated and aliphatic aldehydes in the presence of catalytic amounts (2-8% mol) of chiral Ti(IV)/(R)-BINOL complex. (C) 2001 Elsevier Science Ltd. All rights reserved.
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