4.8 Article

Iridium complex catalyzed carbonylative alkyne-alkyne coupling for the synthesis of cyclopentadienones

Journal

ORGANIC LETTERS
Volume 3, Issue 8, Pages 1217-1219

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol015708c

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Catalytic carbonylative alkyne-alkyne coupling proceeds using iridium-phosphine complexes under carbon monoxide at atmospheric pressure or a partial pressure of 0.2 atm. This reaction provides various cyclopentadienones in high isolated yields.

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